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The atomic structure of polar and non-polar InGaN quantum wells and the green gap problem.

Identifieur interne : 000239 ( Main/Exploration ); précédent : 000238; suivant : 000240

The atomic structure of polar and non-polar InGaN quantum wells and the green gap problem.

Auteurs : C J Humphreys [Royaume-Uni] ; J T Griffiths [Royaume-Uni] ; F. Tang [Royaume-Uni] ; F. Oehler [France] ; S D Findlay [Australie] ; C. Zheng [Australie] ; J. Etheridge [Australie] ; T L Martin [Royaume-Uni] ; P A J. Bagot [Royaume-Uni] ; M P Moody [Royaume-Uni] ; D. Sutherland [Royaume-Uni] ; P. Dawson [Royaume-Uni] ; S. Schulz [Irlande (pays)] ; S. Zhang [Royaume-Uni] ; W Y Fu [Royaume-Uni] ; T. Zhu [Royaume-Uni] ; M J Kappers [Royaume-Uni] ; R A Oliver [Royaume-Uni]

Source :

RBID : pubmed:28196629

Abstract

We have used high resolution transmission electron microscopy (HRTEM), aberration-corrected quantitative scanning transmission electron microscopy (Q-STEM), atom probe tomography (APT) and X-ray diffraction (XRD) to study the atomic structure of (0001) polar and (11-20) non-polar InGaN quantum wells (QWs). This paper provides an overview of the results. Polar (0001) InGaN in QWs is a random alloy, with In replacing Ga randomly. The InGaN QWs have atomic height interface steps, resulting in QW width fluctuations. The electrons are localised at the top QW interface by the built-in electric field and the well-width fluctuations, with a localisation energy of typically 20meV. The holes are localised near the bottom QW interface, by indium fluctuations in the random alloy, with a localisation energy of typically 60meV. On the other hand, the non-polar (11-20) InGaN QWs contain nanometre-scale indium-rich clusters which we suggest localise the carriers and produce longer wavelength (lower energy) emission than from random alloy non-polar InGaN QWs of the same average composition. The reason for the indium-rich clusters in non-polar (11-20) InGaN QWs is not yet clear, but may be connected to the lower QW growth temperature for the (11-20) InGaN QWs compared to the (0001) polar InGaN QWs.

DOI: 10.1016/j.ultramic.2017.01.019
PubMed: 28196629


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<name sortKey="Sutherland, D" sort="Sutherland, D" uniqKey="Sutherland D" first="D" last="Sutherland">D. Sutherland</name>
<affiliation wicri:level="4">
<nlm:affiliation>School of Physics and Astronomy, Photon Science Institute, University of Manchester, Manchester M13 9PL, UK. Electronic address: danny.sutherland@manchester.ac.uk.</nlm:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>School of Physics and Astronomy, Photon Science Institute, University of Manchester, Manchester M13 9PL</wicri:regionArea>
<orgName type="university">Université de Manchester</orgName>
<placeName>
<settlement type="city">Manchester</settlement>
<region type="nation">Angleterre</region>
<region nuts="2" type="region">Grand Manchester</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Dawson, P" sort="Dawson, P" uniqKey="Dawson P" first="P" last="Dawson">P. Dawson</name>
<affiliation wicri:level="4">
<nlm:affiliation>School of Physics and Astronomy, Photon Science Institute, University of Manchester, Manchester M13 9PL, UK. Electronic address: philip.dawson@manchester.ac.uk.</nlm:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>School of Physics and Astronomy, Photon Science Institute, University of Manchester, Manchester M13 9PL</wicri:regionArea>
<orgName type="university">Université de Manchester</orgName>
<placeName>
<settlement type="city">Manchester</settlement>
<region type="nation">Angleterre</region>
<region nuts="2" type="region">Grand Manchester</region>
</placeName>
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</author>
<author>
<name sortKey="Schulz, S" sort="Schulz, S" uniqKey="Schulz S" first="S" last="Schulz">S. Schulz</name>
<affiliation wicri:level="1">
<nlm:affiliation>Tyndall National Institute, Lee Maltings Complex, Dyke Parade, Cork, Ireland. Electronic address: stefan.schulz@tyndall.ie.</nlm:affiliation>
<country xml:lang="fr">Irlande (pays)</country>
<wicri:regionArea>Tyndall National Institute, Lee Maltings Complex, Dyke Parade, Cork</wicri:regionArea>
<wicri:noRegion>Cork</wicri:noRegion>
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<author>
<name sortKey="Zhang, S" sort="Zhang, S" uniqKey="Zhang S" first="S" last="Zhang">S. Zhang</name>
<affiliation wicri:level="4">
<nlm:affiliation>Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS, UK. Electronic address: siyuan.zhang@mpie.de.</nlm:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS</wicri:regionArea>
<orgName type="university">Université de Cambridge</orgName>
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<settlement type="city">Cambridge</settlement>
<region type="country">Angleterre</region>
<region type="région" nuts="1">Angleterre de l'Est</region>
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</affiliation>
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<author>
<name sortKey="Fu, W Y" sort="Fu, W Y" uniqKey="Fu W" first="W Y" last="Fu">W Y Fu</name>
<affiliation wicri:level="4">
<nlm:affiliation>Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS, UK. Electronic address: wyfu@hku.hk.</nlm:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS</wicri:regionArea>
<orgName type="university">Université de Cambridge</orgName>
<placeName>
<settlement type="city">Cambridge</settlement>
<region type="country">Angleterre</region>
<region type="région" nuts="1">Angleterre de l'Est</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Zhu, T" sort="Zhu, T" uniqKey="Zhu T" first="T" last="Zhu">T. Zhu</name>
<affiliation wicri:level="4">
<nlm:affiliation>Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS, UK.</nlm:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS</wicri:regionArea>
<orgName type="university">Université de Cambridge</orgName>
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<settlement type="city">Cambridge</settlement>
<region type="country">Angleterre</region>
<region type="région" nuts="1">Angleterre de l'Est</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Kappers, M J" sort="Kappers, M J" uniqKey="Kappers M" first="M J" last="Kappers">M J Kappers</name>
<affiliation wicri:level="4">
<nlm:affiliation>Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS, UK. Electronic address: mjk30@cam.ac.uk.</nlm:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS</wicri:regionArea>
<orgName type="university">Université de Cambridge</orgName>
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<settlement type="city">Cambridge</settlement>
<region type="country">Angleterre</region>
<region type="région" nuts="1">Angleterre de l'Est</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Oliver, R A" sort="Oliver, R A" uniqKey="Oliver R" first="R A" last="Oliver">R A Oliver</name>
<affiliation wicri:level="4">
<nlm:affiliation>Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS, UK. Electronic address: rao28@cam.ac.uk.</nlm:affiliation>
<country xml:lang="fr">Royaume-Uni</country>
<wicri:regionArea>Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge CB3 0FS</wicri:regionArea>
<orgName type="university">Université de Cambridge</orgName>
<placeName>
<settlement type="city">Cambridge</settlement>
<region type="country">Angleterre</region>
<region type="région" nuts="1">Angleterre de l'Est</region>
</placeName>
</affiliation>
</author>
</analytic>
<series>
<title level="j">Ultramicroscopy</title>
<idno type="eISSN">1879-2723</idno>
<imprint>
<date when="2017" type="published">2017</date>
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<front>
<div type="abstract" xml:lang="en">We have used high resolution transmission electron microscopy (HRTEM), aberration-corrected quantitative scanning transmission electron microscopy (Q-STEM), atom probe tomography (APT) and X-ray diffraction (XRD) to study the atomic structure of (0001) polar and (11-20) non-polar InGaN quantum wells (QWs). This paper provides an overview of the results. Polar (0001) InGaN in QWs is a random alloy, with In replacing Ga randomly. The InGaN QWs have atomic height interface steps, resulting in QW width fluctuations. The electrons are localised at the top QW interface by the built-in electric field and the well-width fluctuations, with a localisation energy of typically 20meV. The holes are localised near the bottom QW interface, by indium fluctuations in the random alloy, with a localisation energy of typically 60meV. On the other hand, the non-polar (11-20) InGaN QWs contain nanometre-scale indium-rich clusters which we suggest localise the carriers and produce longer wavelength (lower energy) emission than from random alloy non-polar InGaN QWs of the same average composition. The reason for the indium-rich clusters in non-polar (11-20) InGaN QWs is not yet clear, but may be connected to the lower QW growth temperature for the (11-20) InGaN QWs compared to the (0001) polar InGaN QWs.</div>
</front>
</TEI>
<affiliations>
<list>
<country>
<li>Australie</li>
<li>France</li>
<li>Irlande (pays)</li>
<li>Royaume-Uni</li>
</country>
<region>
<li>Angleterre</li>
<li>Angleterre de l'Est</li>
<li>Grand Manchester</li>
<li>Oxfordshire</li>
</region>
<settlement>
<li>Cambridge</li>
<li>Manchester</li>
<li>Oxford</li>
</settlement>
<orgName>
<li>Université d'Oxford</li>
<li>Université de Cambridge</li>
<li>Université de Manchester</li>
</orgName>
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<tree>
<country name="Royaume-Uni">
<region name="Angleterre">
<name sortKey="Humphreys, C J" sort="Humphreys, C J" uniqKey="Humphreys C" first="C J" last="Humphreys">C J Humphreys</name>
</region>
<name sortKey="Bagot, P A J" sort="Bagot, P A J" uniqKey="Bagot P" first="P A J" last="Bagot">P A J. Bagot</name>
<name sortKey="Dawson, P" sort="Dawson, P" uniqKey="Dawson P" first="P" last="Dawson">P. Dawson</name>
<name sortKey="Fu, W Y" sort="Fu, W Y" uniqKey="Fu W" first="W Y" last="Fu">W Y Fu</name>
<name sortKey="Griffiths, J T" sort="Griffiths, J T" uniqKey="Griffiths J" first="J T" last="Griffiths">J T Griffiths</name>
<name sortKey="Kappers, M J" sort="Kappers, M J" uniqKey="Kappers M" first="M J" last="Kappers">M J Kappers</name>
<name sortKey="Martin, T L" sort="Martin, T L" uniqKey="Martin T" first="T L" last="Martin">T L Martin</name>
<name sortKey="Moody, M P" sort="Moody, M P" uniqKey="Moody M" first="M P" last="Moody">M P Moody</name>
<name sortKey="Oliver, R A" sort="Oliver, R A" uniqKey="Oliver R" first="R A" last="Oliver">R A Oliver</name>
<name sortKey="Sutherland, D" sort="Sutherland, D" uniqKey="Sutherland D" first="D" last="Sutherland">D. Sutherland</name>
<name sortKey="Tang, F" sort="Tang, F" uniqKey="Tang F" first="F" last="Tang">F. Tang</name>
<name sortKey="Zhang, S" sort="Zhang, S" uniqKey="Zhang S" first="S" last="Zhang">S. Zhang</name>
<name sortKey="Zhu, T" sort="Zhu, T" uniqKey="Zhu T" first="T" last="Zhu">T. Zhu</name>
</country>
<country name="France">
<noRegion>
<name sortKey="Oehler, F" sort="Oehler, F" uniqKey="Oehler F" first="F" last="Oehler">F. Oehler</name>
</noRegion>
</country>
<country name="Australie">
<noRegion>
<name sortKey="Findlay, S D" sort="Findlay, S D" uniqKey="Findlay S" first="S D" last="Findlay">S D Findlay</name>
</noRegion>
<name sortKey="Etheridge, J" sort="Etheridge, J" uniqKey="Etheridge J" first="J" last="Etheridge">J. Etheridge</name>
<name sortKey="Zheng, C" sort="Zheng, C" uniqKey="Zheng C" first="C" last="Zheng">C. Zheng</name>
</country>
<country name="Irlande (pays)">
<noRegion>
<name sortKey="Schulz, S" sort="Schulz, S" uniqKey="Schulz S" first="S" last="Schulz">S. Schulz</name>
</noRegion>
</country>
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</affiliations>
</record>

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